Sorption of Atrazine, Propazine, Deethylatrazine, Deisopropylatrazine and Hydroxyatrazine onto Organovermiculite
نویسندگان
چکیده
Estudou-se a interação de atrazina (AT), propazina (PROP), desetil-atrazina (DEA), deisopropilatrazina (DIA) e hidroxi-atrazina (HAT) com o argilomineral vermiculita saturado com K (VTK) e com VTK modificada pela incorporação de hexadeciltrimetil-amônio (HDTMA-VT) no espaço interlamelar. A VTK bruta teve interação desprezível com AT, PROP e DEA, interação moderada com DIA e forte interação com HAT. No caso do material HDTMA-VT as porcentagens de remoção em meio aquoso (concentrações iniciais entre 0,05 a 1,00 mg L) foram: 56 – 63% para AT, 43 – 45% para DEA, 30 – 24% para DIA, 12 – 19% para HAT e 77 – 78% para PROP. As taxas de sorção de AT, DEA e PROP em HDTMA-VT foram significativamente aumentadas com relação a VTK. Força iônica e pH tiveram pouca influência na sorção. A dessorção dos compostos previamente sorvidos sobre os minerais HDTMA-VT variou de 20 a 30% após um tempo de contacto de 24 h.
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